It WILL radiate down into your structure. Ceramic additives are insulation. They slow down heat transfer, they don't prevent it. The surface will heat up - just a little slower than if you didn't have the insulative paint. There's nowhere for the heat to go on the underside. The 6" thick foam inside the wing is insulation, too.
You can get some pigments that are made to reflect more IR than carbon black (the standard black color). If you want to see if it's good enough, paint a sample panel, put it in the sun in July at 10 am, and take temperature measurements every half hour or so.
However...
If you're worried about what color to make it before you've started building, get another hobby. You won't ever finish an airplane. You'll spend several thousand dollars, and a couple of hundred hours building, and you'll decide it's not for you and sell it at a loss.
If a someone signs up for piano lessons that's never even sat at the keyboard, and his first question is what color his tux should be when he makes his debut with the NY Phil, you know he never will. He shouldn't buy that concert grand piano.
If you want to work with computer graphics, there's nothing wrong with that. It's not building an airplane. Sorry to be blunt, but I've seen it too many times.